Finally found a solution to my own problem! Went to Settings-->Plugins and Extras-->Advanced and ticked the 'Disable window recovery' option in the dialog box. Rebooted and...problem solved! Doesn't seem to have any bad side effects. Hope my little ordeal can help others.

First let me thank the developers for offering such a solid application as Dexpot. This is one of the few programs that actually makes Windows 8 user experience somewhat pleasant! And it's free for consumers, which is awesome! Nevertheless, I have an issue that I can't seem to solve. I couldn't find...